教育与研究经历: 1975年-1978年,betway官方app (原新乡师范学院),化学系,大学 1978年-1981年,betway官方app (原新乡师范学院)化学系,研究生/硕士 1999年-2001年,日本横滨国立大学,化学与材料工程系, 研究生/博士 1981年-1987年,betway官方app ,化学化工学学院,助教、讲师 1987年-1989年,英国London大学,大学学院化学系,访问学者 1987年-1991年,betway官方app ,化学化工学学院,副教授 1992年-1994年,英国Surrey大学,化学系,Research Fellow 1992年-至今, betway官方app ,化学化工学学院,教授、博士生导师 联系方式: 电话:0373-3325805 E-mail: Jwang@henannu.edu.cn 主讲课程: 《物理化学》、《物理化学新进展》、《绿色化学》 研究领域与兴趣: 1. 功能溶液化学 2. 基于离子液体的绿色化学 3. 生物质新能源高效利用 近年来主持的主要科研项目: 1. 国家863项目(2007AA05Z454): 离子液体分级处理木质纤维素原料制备燃料乙醇和氢能新技术 2. 国家973前期专项(2011CB211702):功能离子液体低温溶解/催化木质素生成液态烷烃燃料的研究 3. 国家863项目(子课题)( 2004AA649030):基于离子液体的酸性有害气体资源化利用的新技术—功能化离子液体的制备与物性研究 4. 国家973项目(子课题)( 2009CB219902) 离子液体的合成、表征及物理化学性质研究 5. 国家自然科学基金重点项目(21133009):离子液体复杂体系化学热力学与分子间相互作用研究 6. 国家自然科学基金(21273062): pH 响应离子液体的溶液化学研究 7. 国家自然科学基金(20873036):离子液体双水相的微观结构与萃取分离性能研究 8. 国家自然科学基金(20573034):室温离子液体在溶液中的簇集行为研究 9. 国家自然科学基金(20273019):室温离子液体中溶质-溶剂相互作用规律研究 10. 国家自然科学基金(29973009):锂电池电解质溶液中离子溶剂化的热力学和谱学研究 11. 国家自然科学基金(29573102):水溶液中电解质-糖相互作用规律的热力学研究 12. 国家教委优秀年轻教师资助计划: 氨基酸在蛋白质变性剂水溶液中的热力学和传输性质研究 13. 教育部高等学校骨干教师: 锂电池电解质溶液的结构与性能 14. 教育部高等学校博士点专项科研基金(20060476003):咪唑类离子液体在分子溶剂中的溶剂化学行为研究 15. 河南省杰出青年基金: 水溶液中电解质糖-模型生物分子相互作用的热力学研究 16. 河南省杰出人才计划(08420050015):功能化离子液体的设计、合成及对生物大分子的选择性分离 17. 河南省中原学者计划(092101510300):离子液体在绿色分离和先进材料制备中的作用机制研究 18. 日本三菱化学公司研发基金: 液态和胶态介质中离子迁移数测定方法和实验装置的研究与开发 代表性论文与专利: 论文: 在 J.Am.Chem. Soc., Angew. Chem. Int. Ed., Chem. Soc. Rev., Chem. Eur. J., Chem.Comm., Green Chem., Environ.Sci.Technol., J.Phys.Chem., ChemSusChem等SCI期刊发表论文200余篇,被SCI引用3700余次,代表性论文如下: 1.张虎成,张立伟,王键吉,Grafting and Coloring onto Silver Nanoparticles by Photoinduced Surface Modification, J. Am. Chem. Soc., 131 (37), 13206–13207 (2009) 2.任运来,闫孟杰,王键吉,张宗超,姚开胜,Selective Reductive Cleavage of Inert Aryl C-O Bonds by an Iron Catalyst, Angew. Chem. Int. Ed., 52, 12674-12678 (2013). 3.张锁江,孙剑,张晓春,辛加余,苗晴晴,王键吉,Ionic Liquid-based Green Processes for Energy Production, Chem. Soc. Rev, 2014, DOI: 10.1039/c3cs60409h 4.裴渊超,王键吉,轩小朋,樊静,范貌宏,Factors affecting ionic liquids based removal of anionic dyes from water, Environ. Sci. Technol., 41, 5090-5095 (2007) 5.王慧勇,张腊梅,王键吉,李志勇,张锁江,The First Evidence for Unilamellar Vesicle Formation of Ionic Liquids in Aqueous Solutions, Chem. Commun., 49, 5222-5224 (2013) 6.姚开胜,卢伟伟,李鑫莹,王键吉,元炯亮,Tunable Synthesis of Ag Films at Ionic Liquid-aqueous Interfaces,Chem. Commun., 49, 1398-1400(2013). 7.王慧勇,王键吉,范貌宏,Extraction of Ionic Liquids from Aqueous Solutions by Humic Acid: An Environmentally Benign, Inexpensive and Simple Procedure,Chem. Commun., 48, 392-394 (2012). 8. 卢伟伟,宋应利,姚开胜,王键吉,Thermal-Induced Formation of a Three-Dimensional Nanoplasmonic Sensor from Ag Nanocubes with High Stability and Reusability, Chem. Eur. J., 20, 3636-3645 (2014). 9.熊大珍,王慧勇,李志勇,王键吉,Recovery of Ionic Liquids with Aqueous Two-Phase Systems Induced by Carbon Dioxide, ChemSusChem., 5,2255-2261 (2012). 10.吕本莲,许爱荣,王键吉,Cation Does Matter: How Cationic Structure Affects the Dissolution of Cellulose in Ionic Liquids, Green Chem., 16, 1326-1335 (2014) 11.熊大珍,李志勇,王慧勇,王键吉,Selective Separation of Aliphatic and Aromatic Amines with CO2 Switchable Ionic Liquids Aqueous Two-phase Systems, Green Chem., 15, 1941-1948 (2013). 12.李志勇,刘欣欣,裴渊超,王键吉,Design of Environmentally Friendly Ionic Liquids Aqueous Two-phase Systems for the Efficient and High Activity Extraction of Proteins, Green Chem., 14, 2941-2950 (2012). 13.陈清泰,许爱荣,李志勇,王键吉,Influence of Anionic Structure on the Dissolution of Chitosan in 1-butyl-3-methylimidazolium-based Ionic Liquids, Green Chem., 13, 3446-3452 (2011). 14.朱安莲,李凌君,王键吉,卓克垒,Direct Nucleophilic Substitution Reaction of Alcohols Mediated by a zinc-based Ionic Liquid, Green Chem., 13, 1244-1250 (2011). 15.姚开胜,李鑫莹,卢伟伟,王键吉,Tailoring the Properties of Aqueous/Ionic Liquids Interface for Tunable Synthesis and Self-Assembly of ZnS Nanoparticles, J. Mater. Chem. A, 2, 5140-5148 (2014). 16.王慧勇,冯青琴,王键吉,张虎成,Salt Effect on the Aggregation Behavior of 1-Decyl-3-methylimidazolium Bromide in Aqueous Solutions J. Phys. Chem. B, 114,1380-13879 (2010). 17.赵玉灵,刘晓敏,王键吉,张锁江,Insight into Co-solvent Effect of Cellulose Dissolution in Imidazolium-based Ionic Liquid Systems, J. Phys. Chem. B, 117, 9042-9049. 18.赵玉灵,刘晓敏,吕兴梅,张锁江,王键吉,The Behavior of Ionic Liquids under High Pressure: A Molecular Dynamics Simulation, J. Phys. Chem. B, 116, 10876-10884 (2012). 19.赵扬,高山娇,王键吉,汤俊明,Aggregation of Ionic Liquids [Cnmim]Br (n = 4, 6, 8, 10, 12) in D2O: A NMR Study, J. Phys. Chem. B, 112, 2031-2039 (2008). 20.王键吉,王慧勇,张社利,张虎成,赵扬,Conductivities, Volumes, Fluorescence and Aggregation Behavior of Ionic Liquids [C4mim][BF4] and [Cnmim]Br (n=4, 6, 8, 10, 12) in Aqueous Solutions, J. Phys. Chem. B, 111, 6181-6188 (2007). 21.张虎成, 王键吉,郑洪河,卓克垒,赵扬,Interactions of Nanosized Al2O3and ZnO with Poly(ethylene oxide)-NaSCN Polymer Electrolytes, J. Phys. Chem. B, 109, 2610-2616 (2005). 22.张虎成,轩小朋,王键吉,汪汉卿,Vibrational Spectroscopic Studies on Interactions in PEO- NaSCN-urea Composites, J. Phys. Chem. B, 108, 1563-1569 (2004). 23.郑勇,轩小朋,王键吉,范貌宏,The Enhanced Dissolution of β-Cyclodextrin in Some Hydrophilic Ionic Liquids J. Phys. Chem. A, 114, 3926-3931 (2010). 24.轩小朋,张虎成,王键吉,汪汉卿,Vibrational Spectroscopic and Density Functional Studies on Ion Solvation and Association of Lithium Tetrafluorobrate in Acetonitrile, J. Phys. Chem. A, 108, 7513-7521 (2004). 25.许爱荣,王键吉,王慧勇,Effects of Anionic Structure and Lithium Salts Addition on the Dissolution of Cellulose in 1-butyl-3-methylimidazolium-based Ionic Liquid Solvent Systems, Green Chem., 12, 268-275 (2010) 26.王键吉, 裴渊超,赵扬,胡治国,Recovery of Amino Acids by Imidazolium Based Ionic Liquids from Aqueous Media, Green Chem., 7, 196-202 (2005) 27.王键吉,田勇,赵扬, 卓克垒,A Volumetric and Viscosity Study for the Mixtures of 1-n-butyl- 3- methylimidazolium Tetrafluoroborate Ionic Liquid with Acetonitrile, Dichloromethane, 2-Butanone and N,N-dimethylformamide, Green Chem., 5, 618-622 (2003) 28.张新迎,范学森,牛红英,王键吉,An Ionic Liquid as a Recyclable Medium for the Green Preparation of α, α’-bis (substituted benzylidene)cycloalkanones Catalyzed by FeCl3·6H2O, Green Chem., 5, 267-269 (2003). 29.吴长增,王键吉,李志勇,荆俊,王慧勇,Relative Hydrophobicity between the Phases and Partition of Cytochrome-c in Glycine Ionic Liquids Aqueous Two-phase Systems, J. Chromat. A., 1305, 1-6 (2013). 30.吴长增,王键吉,王慧勇,裴渊超,李志勇,Effect of Anionic Structure on the Phase Formation and Hydrophobicity of Amino Acid Ionic Liquids Aqueous Two-phase Systems, J. Chromat. A., 1218, 8587-8593 (2011) 31.李志勇,裴渊超,王慧勇,樊静,王键吉,Ionic liquids based aqueous two-phase systems and their applications in green separation process, Trends Anal. Chem., 29, 1336-1346 (2010). 32.王慧勇,王键吉,张社利,裴渊超,卓克垒,Ionic Association of the Ionic Liquids [C4mim][BF4], [C4mim][PF6], and [Cnmim]Br in Molecular Solvents. ChemPhysChem., 10, 2516–25232 (2009) 33.王慧勇,王键吉,张仕彪,Binding Gibbs Energy of Ionic Liquids to Calf thymus DNA: a Fluorescence Spectroscopy Study, Phys. Chem. Chem. Phys., 13, 3906-3910 (2011)
34.赵玉灵,刘晓敏,王键吉,张锁江,Effects of Anionic Structure on the Dissolution of Cellulose in Ionic Liquids Revealed by Molecular Simulation, Carbonhydrate Polymers, 94, 723-730 (2013). 35.许爱荣,张亚娟,赵扬,王键吉,Cellulose Dissolution at Ambient Temperature: Role of Preferential Solvation of Cations of Ionic Liquids by a Cosolvent, Carbonhydrate Polymers, 92, 540-544 (2013). 36.赵扬,崔桂荣,王键吉,范貌宏,Effects of Ionic Liquids on the Characteristics of Synthesized Nano Fe(0) Particles, Inorg. Chem., 48, 10435–10441 (2009) 37.赵扬,陈震华,王慧勇,王键吉,Crystallization Control of CaCO3by Ionic Liquids in Aqueous Solution, Crystal Growth & Design, 9, 4984-4986 (2009)
38.李鑫莹,姚开胜,卢伟伟,王键吉,Facile Interfacial Synthesis of Gold Micro/nanostructures and Their Applications for Efficient Surface Enhanced Raman Scattering , CrystEngComm, 15, 1289-1292 (2013). 39.周海梅,吕萍,申圆圆,王键吉,樊静,Identification of Degradation Products of Ionic Liquids in an Ultrasound Assisted Zero-valent iron Activated Carbon Micro-electrolysis System and Their Degradation Mechanism, Water Res., 47, 3514-3522 (2013) . 40.周海梅,申圆圆,吕萍,王键吉,樊静,Degradation of 1-butyl-3-methylimidazolium Chloride Ionic Liquid by Ultrasound and Zero-valent iron/activated Carbon, Separ. Purif. Technol., 104, 208-213 (2013). 41.裴渊超,王键吉,武坤,轩小朋,卢新杰,Ionic Liquid-based Aqueous Two-phase Extraction of Selected Proteins, Separ. Purif. Technol., 64, 288-295 (2009) 42. 樊静,范云场,裴渊超,武坤,王键吉, Solvent Extraction of Selected Endocrine-disrupting Phenols using Ionic Liquids, Sep. Purif. Technol., 61, 324-331 (2008) 43.张虎成, 王键吉, 轩小朋,卓克垒,FT-IR Studies on Interactions of AlCl3with PEO-NaSCN Polymer Electrolytes, Electrochim. Acta, 51, 3244-3248 (2006) 44.轩小朋, 王键吉,汪汉卿, Theoretical Insights into PF6- and its Alkali Metal Ion Pairs: Geometries and Vibrational Frequencies, Electrochim. Acta, 50, 4196-4201 (2005) 45.轩小朋, 王键吉,赵扬,朱建军,Experimental and Computational Studies on the Solvation of Lithium Tetrafluorobrate in Dimethylsulfoxide, J. Raman Spectrosc., 38, 865-872 (2007) 46.轩小朋,张虎成,王键吉,汪汉卿, Raman Spectroscopic and DFT Studies on Solutions of NaBF4in N,N-dimethylformamide, J. Raman Spectrosc., 34, 465-470 (2003) 47.冯青琴,王慧勇,张仕彪,王键吉,Aggregation Behavior of 1-Dodecyl-3-methylimidazolium Bromide Ionic Liquid in non-aqueous Solvents, Colloids and Surfaces A: Physicochem. Eng. Aspects, 367, 7-11 (2010) 48.轩小朋, 王键吉,赵扬,张虎成, FT-Raman Spectroscopic Evidences for the Preferential Solvation of Sodium Tetrafluorobrate in Acetonitrile-based Mixed Solvents, Spectrochim. Acta A, 62, 500-505 (2005) 49.王键吉,吴艳平,轩小朋,汪汉卿, Ion-molecule Interactions in Solutions of Lithium Perchlorate in Propylene Carbonate + Diethyl Carbonate Mixtures: an IR and Molecular Orbital Study, Spectrochim. Acta, A, 58, 2097-2104 (2002) 50.朱安莲,王键吉,韩丽君,范貌宏, Measurements and Correlation of Viscosities and Conductivities for the Mixtures of Imidazolium Ionic Liquids with Molecular Solutes, Chem. Eng. J., 147, 27-35 (2009) 51.王键吉,张仕彪,王慧勇,裴渊超, Apparent Molar Volumes and Electrical Conductance of Ionic Liquids [Cnmim]Br (n=8, 10, 12) in Ethylene Glycol, N,N-Dimethylformamide, and Dimethylsulfoxide at 298.15 K, J. Chem. Eng. Data, 54, 3252-3258 (2009) 52.吴长增,王键吉,裴渊超,王慧勇,李志勇,Salting-Out Effect of Ionic Liquids on Poly(propylene glycol) (PPG): Formation of PPG + Ionic Liquid Aqueous Two-Phase Systems, J. Chem. Eng. Data, 55, 5004-5008 (2010) 53.裴渊超,王键吉,刘丽,武坤,赵扬,Liquid-liquid Equilibria of Aqueous Biphasic Systems Containing Selected Imidazolium Ionic Liquids and Salts, J. Chem. Eng. Data, 52, 2026-2031 (2007) 54.李志勇,裴渊超,刘丽,王键吉, (Liquid+liquid) Equilibria for (Acetate-based Ionic Liquids + Inorganic Salts) Aqueous Two-phase Systems, J. Chem. Thermodyn. 2010, 42, 932-937 (2010) 55.王键吉,朱安莲,赵扬,卓克垒,Excess Molar Volumes and Excess Logarithm Viscosityes for Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluophosphate with Some Organic Compounds, J. Solution Chem., 34, 585-596 (2005) 专利: 1.樊静,吴春来,王键吉,彭传云,魏娅方,梁峰,茜素紫键合硅胶固相萃剂的合成方法,中国发明专利,专利号: ZL 200710054167.6
2.刘振,王键吉, 尹卫平, 杨敏,天然纤维素原料经离子液体分级处理一步发酵制备乙醇的方法,中国发明专利,专利号:ZL 200810095798.7 3.刘振,王键吉,尹卫平,任运来,任云利,利用离子液体生产乙醇的方法,中国发明专利,专利号:ZL201010030128.4 4.刘振,王键吉,郝静静,陈竞一,常庆辉,一种磁场辅助气提发酵生产乙醇的方法,中国发明专利,专利号: ZL 201110171615.7 5.刘振,王键吉,常庆辉,陈竞一,张辉,孙鲜明,马建华,一种发酵制氢中氢气的分离装置,中国实用新型专利,专利号:,ZL 201220353776.8 6.王键吉,许爱荣,樊静,轩小朋,一种纤维素的溶剂,中国发明专利,申请号:200910065084.6 著作: 张锁江, 王键吉, 吕兴梅, 周清,《Structures and Interactions of Ionic Liquids》, Springer, 2014 成果奖励: 1. 离子液体的构效关系及其化学工程基础研究, 2010年国家自然科学二等奖 2. 糖和氨基酸与电解质弱相互作用的热力学研究,2004年河南省科技进步一等奖 3. 锂离子电池电解质的微观结构研究,2009年河南省科技进步一等奖
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