环境样品中敌百虫的流动注射化学发光法测定及反应机理探讨

摘要:

利用敌百虫在碱性介质中能够增敏鲁米诺-铁氰化钾体系产生的化学发光性能,建立了一种测定敌百虫的流动注射化学发光分析新方法,并对反应机理进行了探讨.在最佳实验条件下,对实际环境水样和蔬菜样品中残留的敌百虫进行测定,结果显示,其加标回收率在86.4%~94.8%之间,相对标准偏差为1.03%~1.83%;该方法的线性范围为5×10-7~5×10-3 g/L,检测限为1.13×10-7 g/L.

Based on the enhancement of trichlorfon on chemiluminescence of the luminol-K_3 Fe（CN）_6 system in alkaline solution,a novel chemiluminescence method was developed for determination of trichlorfon with flow injection technique,and the possible mechanism was also discussed.The trichlorfon in actual waster and vegetables were successfully determined under the optimal conditions with the recovery of standard addition of 86.4%-94.8%.The relative standard deviation was 1.03%-1.83%.The linear standard curve of this new method was from 5×10（-7） to 5×10（-3） g/L and the detection limit was 1.13×10（-7） g/L.

作者:

杨波 范顺利 秦歌 朱桂芬

Yang Bo;Fan Shunli;Qin Ge;Zhu Guifen(Xinxiang Drainage Engineering Co.,LTD.,Xinxiang 453000,China;School of Environment,Key Laboratory for Yellow River and Huai River Water Environment and Pollution Control,Ministry of Education,Henan Key Laboratory for Environmental pollution Control,Henan Normal University,Xinxiang 453007,China;College of life science and technology,Xinxiang University,Xinxiang 453000,China)

机构地区:

新乡市排水工程有限公司 betway官方app 环境学院黄淮水环境与污染防治省部共建教育部重点实验室河南省环境污染控制重点实验室 新乡学院生命科学技术学院

出处:

《betway官方app 学报：自然科学版》 CAS 北大核心 2018年第5期61-67,共7页

基金:

河南省基础与前沿技术研究计划项目(132300413209)

关键词:

敌百虫 流动注射 化学发光 固相萃取 环境样品

trichlorfon flow-injection chemiluminescence solid-phase extraction environmental samples

分类号:

X839.2 [环境科学与工程—环境工程]

环境样品中敌百虫的流动注射化学发光法测定及反应机理探讨.pdf