水泥基材料氯离子测试方法评价研究

摘要：

氯离子是影响水泥基材料耐久性的重要因素之一,准确测量氯离子浓度,是研究水泥基材料固化氯离子能力的基础.水泥基材料中的掺合料在酸溶时有难溶絮状物质生成,此物质对氯离子有一定的吸附性,导致氯离子测量难度增加.基于此通过实验研究不同测量方法对水泥基材料中氯离子的测量效果.实验分析表明:电位滴定法可以避免人为因素的影响,在保证电极正确处理和仪器定期校准的情况下,测试准确度较高,重复性较好;佛尔哈德法,滴定终点明显,而且滴定准确度高,但操作复杂,可直接用于小批量滴定分析;莫尔法操作简单但准确度不高;氯化银比浊法步骤多且准确度低,但适合快速批处理.

Chloride is one of the important factors that affect the durability of cement-based materials. Accurate meas- urement of chloride ion concentration is important for researching the ability of chloride ion binding in cement-based materials. When cement-based materials was dissolved in acid solution, insoluble flocculent substances may generate which can adsorb some chloride ions and increase the difficulty of accurate measuring chloride ions. Based on this, different measurement meth- ods were adopted for cement-based materials to evaluate the measure effect of chloride ion by experiments. Experiment results show that potentiometric titration is able to avoid the influence of human factors, the accuracy is higher and the repeatability is better, in the case of the electrode was treatment correctly and the instrument was periodic calibration. The titration end point of Volhard method is clear, and the test result is accurate, but the operation is complexity and just suitable for small batch ti- tration analysis. Operation of Mohr method is relatively simple, but the accuracy is not very high. Measurement process of tur- bidimetry is complex and the accuracy is lower, but it is suitable for handled in batch.

作者：

毕文彦 万剑峰 管学茂 廖虎 宗文英 马亚芬 蒋荣立

机构地区：

河南理工大学物理化学系 中国矿业大学化工学院 河南理工大学机械学院 河南理工大学材料学院 内蒙古黄陶勒盖煤炭有限责任公司世林化工分公司

出处：

《betway官方app 学报：自然科学版》 CAS 北大核心 2015年第3期89-93,共5页

基金：

国家自然科学基金(21101059 51272068)

关键词：

莫尔法 佛尔哈德法 氯化银比浊法 电位滴定法 评价

Mohr method Volhard method turbidimetry potentiometric titration evaluation

分类号：

TQ124.4 [化学工程—无机化工]

水泥基材料氯离子测试方法评价研究.pdf