Synthesis,Characterization and Properties of 2,2-di{4-di[2,3(3,4)-Dicyanophenoxy]Phenyl}Propane

摘要:

以二甲基亚砜为溶剂、氢氧化锂为催化剂,在室温下,将双酚A分别与3-硝基邻苯二腈、4-硝基邻苯二腈反应合成了两种2,2-二{4-二[2,3（3,4）-二氰基苯氧基]苯基}丙烷化合物,产物经-1HNMR,IR,HPLC-MS进行了表征确证,讨论了反应时间及催化剂用量对产率的影响,并对两种产物的紫外-可见光谱及荧光光谱进行研究.

While Bisphenol A and 3-nitro, 4-nitro phthalic nitrile were introduced as raw material, lithium hydroxide was selected as catalyst, 2,2-dil-4-di （2,3-dicyanophenoxy） phenyl-] propane and 2,2-di[4-di （3,4-dicyanophenoxy） pheny＇] propane compounds were synthesized in the dimethyl sulfoxide at room temperature, the target compounds were determined by 1HNMR, IR and HPLC-MS, the effects of reaction time and catalyst dosage on yield were discussed, the UV-vis spectrum and fluorescence spectrum of target products were studied preliminarily.FEWER

作者:

尹彦冰 张浩 宫晶

机构地区:

齐齐哈尔大学化学与化学工程学院

出处:

《betway官方app 学报：自然科学版》 CAS 北大核心 2016年第3期90-93,共4页

基金:

国家自然科学基金(21376126) 黑龙江省普通高校新世纪优秀人才培养计划(1154-NCET-014)

关键词:

2,2-二{4-二[2,3(3,4)-二氰基苯氧基]苯基}丙烷 合成 表征 紫外-可见光谱 荧光光谱

2,2-di{4-di[2,3（3,4）-dicyanophenoxy]phenyl}propanel synthesis characterization UV-vi spectrum flu-orescence spectrum

分类号:

O621.3 [理学—有机化学] O625.6 [理学—有机化学]

2,2-二{4-二[2,3(3,4)-二氰基苯氧基]苯基}丙烷的合成、表征与性质研究.pdf