Synthesis and Characterization of Azobenzene Salicylaldehyde Schiff Base and Metal Complexes
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摘要:
以水杨醛与苯胺为原料合成偶氮苯水杨醛,并进一步与邻氨基苯酚反应生成了相应的Schiff碱,Schiff碱再与锌(Ⅱ)、锰(Ⅱ)、铁(Ⅱ)三种金属离子络合得到三种金属配合物;采用元素分析、电导率测定、紫外光谱和红外拉曼光谱对Schiff碱及其金属配合物的结构进行表征.结果表明:合成的偶氮苯水杨醛缩邻氨基苯酚配体的结构与理论结构相符,且分别与锌(Ⅱ)、锰(Ⅱ)、铁(Ⅱ)离子配位形成了稳定的金属配合物.对配体及其配合物进行了抗菌活性测试,结果表明配合物的抗菌活性强于Schiff碱配体.收起
Azobenzene salieylaldehyde was synthesized with salieylaldehyde and aniline as raw materials. And the corre- sponding Sehiff base was synthesized with the further reaction of o-aminophenol. Three kinds of metal complexes were pre- pared by eomplexing Zn （ Ⅱ ）, Mn（ Ⅱ ）and Ni（ Ⅱ ） with the Schiff base. The structure of the Sehiff base and its metal complexes were characterized by elemental analysis,electric conductance determination, UV spectra and infrared raman spectroscopy. The results show that the azobenzene salicylaldehyde o-aminophenol ligand structure match with the theoretical structure and the stable metal complexes were formed by eomplexing Zn （Ⅱ ）, Mn（ Ⅱ ）and Ni（ Ⅱ ） with the Schiff base. The antibacterial activity of the ligand and complexes were tested and the results showed that the antibacterial activity of the complexes was stronger than that of Schiff base ligand.FEWER
作者:
李艳 李耿
机构地区湖北科技学院核技术与化学生物学院
出处:
《betway官方app 学报：自然科学版》 CAS 北大核心 2016年第1期87-91,共5页
基金:
湖北省自然科学基金(2015CFC780) 湖北科技学院青年项目(KY13040) 湖北省省级大学生创新训练项目(201510927001)
关键词:
偶氮苯水杨醛 邻氨基苯酚 金属配合物 合成 表征 抗菌活性
azobenzene salieylaldehyde o-aminophenol metal complexes synthesis characterization antibacterial ac- tivity
分类号:
O626 [理学—有机化学]
