田苗苗,女,博士,讲师
教育经历:
2010.09-2014.06 许昌学院 化学化工学院 学士
2014.09-2017.06 betway官方app 化学化工学院 硕士
2017.09-2020.07 betway官方app 化学化工学院 博士
工作经历:
2020年8月 至今 betway官方app 讲师
研究领域与兴趣:
1.过渡金属催化的不对称转化、药物分子的设计合成
2.近年来主持的主要科研项目:
3.2022年河南省青年基金,在研
代表性论文:
(1).Miaomiao Tian, Dachang Bai, Guangfan Zheng, Junbiao Chang, Xingwei Li*. Rh(III)-Catalyzed Asymmetric Synthesis of Axially Chiral Biindolyls by Merging C-H Activation and Nucleophilic Cyclization.J. Am. Chem. Soc., 2019, 141: 9527-9532 (ESI高被引).
(2). Miaomiao Tian, Lingyun Yang, Bingxian Liu*, Junbiao Chang*. Synthesis of 9,10-Phenanthrenes via Rh(III)-Catalyzed [4+2] Annulation of 2-Biphenylboronic Acids with Diazo Compounds.Chin. J. Chem.2023,41, 1327-1332
(3). Miaomiao Tian, Bingxian Liu, Jiaqiong Sun, Xingwei Li*. Rh(III)-Catalyzed C-C Coupling of Diverse Arenes and 4-Acyl-1-sulfonyltriazoles via C-H Activation.Org. Lett., 2018, 20: 4946-4949.
(4). Miaomiao Tian, Guangfan Zheng, Xuesen Fan, Xingwei Li*. Rhodium(III)-Catalyzed Redox-Neutral Synthesis of Isoquinolinium Salts via C-H Activation of Imines.J. Org. Chem., 2018, 83: 6477-6488.
(5). Miaomiao Tian, Xifa Yang, Bo Zhang, Bingxian Liu, Xingwei Li*. Rh(III)-Catalyzedα-fluoroalkenylation ofN-nitrosoanilines with 2,2-difluorovinyl tosylates via C–H bond activation.Org. Chem. Front., 2018, 5: 3406–3409.
(6). Miaomiao Tian, Xiaonan Shi, Xinying Zhang,* Xuesen Fan*. Synthesis of 4-Acylpyrazoles from Saturated Ketones and Hydrazones Featured with Multiple C(sp3)−H Bond Functionalization and C−C Bond Cleavage and Reorganization.J. Org. Chem., 2017, 82, 7363−7372.
(7). Miaomiao Tian, Yan He, Xinying Zhang,* Xuesen Fan*. Synthesis of Pyrazolo[5,1-a]isoindoles and Pyrazolo[5,1-a]isoindole-3-carboxamides through One-Pot Cascade Reactions of 1-(2-Bromophenyl)buta-2,3-dien-1-ones with Isocyanide and Hydrazine or Acetohydrazide.J. Org. Chem., 2015, 80, 7447−7455.
(8). Guangfan Zheng, Miaomiao Tian, Youwei Xu, Xiaohong Chen, Xingwei Li*. Rhodium(III)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation.Org. Chem. Front., 2018, 5: 998–1002.
(9). Tian Feng, Miaomiao Tian, Xinying Zhang,* Xuesen Fan*. Tunable Synthesis of Functionalized Cyclohexa-1,3-dienes and 2-Aminobenzophenones/Benzoate from the Cascade Reactions of Allenic Ketones/Allenoate with Amines and Enones.J. Org. Chem., 2018, 83, 5313−5322.
(10). Xiaonan Shi, Miaomiao Tian, Muhua Wang, Xinying Zhang,* Xuesen Fan*. Regioselective Synthesis of Substituted Pyrazoles via [3+2]/[2+3] Cyclization of Saturated Ketone with Hydrazine/Aldehyde Hydrazone.Chin. J. Org. Chem., 2019, 39, 1630−1641.