陈豪华,男,博士,讲师
邮箱:chenhaohua@htu.edu.cn
地址:betway官方app 实训楼606
教育经历:
2013.9-2017.6 海南师范大学 理学学士
2017.9-2023.6 重庆大学 硕博连读 导师:蓝宇教授
工作经历:
2023.7-至今 betway官方app
研究领域与兴趣:
1.过渡金属催化偶联反应和环加成反应的机理及选择性研究;
2.有机小分子催化的不对称反应:理论导向的催化体系优化与设计;
3.有机转化的分子动力学模拟。
代表性论文:
(1). Zhou, W.#; Xi, S.#;Chen, H.#; Jiang, D.; Yang, J.; Liu, S.; He, L.; Qiu, H.; Lan, Y.; Zhang, M. A Bridged Backbone Strategy Enables Collective Syntheses of Strychnan Alkaloids.Nat. Chem.2023,15, 1074–1082(共同一作.)
(2). Xiong, Y.#; Du, Z.#;Chen, H.#; Yang, Z.; Tan, Q.; Zhang, C.; Zhu, L.; Lan, Y.; Zhang, M. Well-Designed Phosphine–Urea Ligand for Highly Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition of Methacrylonitrile: A Combined Experimental and Theoretical Study.J. Am. Chem. Soc.2019,141, 961-971.(共同一作)
(3). Xi, S.#; Dong, J.#;Chen, H.#;Dong, Q.; Yang, J.; Tan, Q.; Zhang, C.; Lan, Y.; Zhang, M. Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylidesto access chiral azabicycles.Sci. Adv.2021,7, eabd5290. (共同一作)
(4).Chen, H.;Li, Y.; Liu, S.; Xiong, Q.; Bai, R.; Wei, D.; Lan, Y. On the mechanism of homogeneous Pt-catalysis: A theoretical view.Coor. Chem. Rev.2021,437, 213863.
(5).Chen, H.;Zhang, T.; Shan, C.; Liu, S.; Song, Q.; Bai, R.; Lan, Y. Mechanism of Brønsted-Base-Mediated Borylation of Propynols: A DFT Study.Org. Lett.2019,21, 4924-4928.
(6).Chen, H.#;Zhu, L.#; Zhong, K.; Yue, X.; Qu, L.-B.; Bai, R.; Lan, Y. Theoretical insight into phosphoric acid-catalyzed asymmetric conjugate addition of indolizines to α,β-unsaturated ketones.Chin. Chem. Lett.2018,29, 1237-1241.
(7). Li, J.#;Chen, H.#;Zhong, Rong.; Zhu, L.; Liu, S; Ding, H.; Yang, J.; Wang, L.; Lan, Y.; Wang, Z. Perfluoroarene Interaction-Controlled Chiral Phosphoric Acid Catalyzed Enantioselective Michael Addition of Difluoroenoxysilanes to Azadienes: a Combination of Experimental and Theoretical Studies.ACS Catal.2022,12, 9655-9663. (共同一作)
(8). Zhang, Z.#;Chen, H.#; Keller, N.#; Xiong, Q.; Liu, L.; Lan, Y.; Bein, T.; Li, J. Dehydrogenative 6π heterocyclization under visible light irradiation and mechanistic insights.Org. Chem. Front.2021,8, 3788-3795. (共同一作)
(9). Xu, L.#;Chen, H.#;Liu, J.#; Zhou, L.; Liu, Q.; Lan, Y.; Xiao, J. Chiral Phosphoric Acid Catalyzed Asymmetric C(sp3)–H Functionalization of Biomass-Derived 2,5-Dimethylfuran via Two Sequential Cope-Type Rearrangements.Org. Chem. Front.2019,6, 1162-1167. (共同一作)
(10). Zheng, B.#;Chen, H.#;Zhu, L.; Hou, X.; Wang, Y.; Lan, Y.; Peng, Y. Formal Asymmetric Cycloaddition of Activated α,β-Unsaturated Ketones with α-Diazomethylphosphonate Mediated by a Chiral Silver SPINOL Phosphate Catalyst.Org. Lett.2019,21, 593-597. (共同一作)